On the server side MTOM processing is enabled through the @BindingType annotation. JBossWS does handle SOAP1.1 and SOAP1.2. Both come with or without MTOM flavours:

MTOM enabled service implementations

package org.jboss.test.ws.jaxws.samples.xop.doclit;
  
import javax.ejb.Remote;
import javax.jws.WebService;
import javax.jws.soap.SOAPBinding;
import javax.xml.ws.BindingType;
  
@Remote
@WebService(targetNamespace = "http://org.jboss.ws/xop/doclit")
@SOAPBinding(style = SOAPBinding.Style.DOCUMENT, parameterStyle = SOAPBinding.ParameterStyle.BARE)
@BindingType(value="http://schemas.xmlsoap.org/wsdl/soap/http?mtom=true")                         (1)
public interface MTOMEndpoint {
  
[...]
}

MTOM enabled clients

Web service clients can use the same approach described above or rely on the Binding API to enable MTOM (Excerpt taken from the org.jboss.test.ws.jaxws.samples.xop.doclit.XOPTestCase):

[...]
Service service = Service.create(wsdlURL, serviceName);
port = service.getPort(MTOMEndpoint.class);
  
// enable MTOM
binding = (SOAPBinding)((BindingProvider)port).getBinding();
binding.setMTOMEnabled(true);