vgreduce command. The vgreduce command shrinks a volume group's capacity by removing one or more empty physical volumes. This frees those physical volumes to be used in different volume groups or to be removed from the system.
pvdisplay command.
# pvdisplay /dev/hda1
-- Physical volume ---
PV Name /dev/hda1
VG Name myvg
PV Size 1.95 GB / NOT usable 4 MB [LVM: 122 KB]
PV# 1
PV Status available
Allocatable yes (but full)
Cur LV 1
PE Size (KByte) 4096
Total PE 499
Free PE 0
Allocated PE 499
PV UUID Sd44tK-9IRw-SrMC-MOkn-76iP-iftz-OVSen7
pvmove command. Then use the vgreduce command to remove the physical volume:
/dev/hda1 from the volume group my_volume_group.
# vgreduce my_volume_group /dev/hda1